Toad Venom?
"Toad smoking," which is a substitute for "toad licking," is done by extracting venom from the Sonoran Desert toad of the Colorado River. The toad's venom - which is secreted when the toad gets angry or scared - contains a hallucinogen called bufotenine that can be dried and smoked to produce a buzz.
http://apnews.myway.com/article/20071204/D8TATFV02.html
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